10Aug 2019

TRIORGANOTIN PHOSPHONATES POLYMERIC CHAINS - SYNTHESIS, INFRARED, MOSSBAUER AND SINGLE CRYSTAL CHARACTERIZATION:THE FIRST ORGANOTIN(IV) PH2- BRIDGED.

  • Laboratoire de Chimie Min?rale et Analytique (LA.CHI.MI.A.), D?partement de Chimie, Facult? des Sciences et Techniques, Universit? Cheikh Anta Diop, Dakar, S?n?gal.
  • D?partement de Physique-Chimie, Facult? des Sciences et Technologies de l?Education et de la Formation (FASTEF), Universit? Cheikh Anta Diop, Dakar, S?n?gal.
  • Institut de Chimie de la Mati?re Condens?e de Bordeaux, CNRS-Universit? de Bordeaux, 87 Avenue du Docteur A. Schweitzer 33608 Pessac, France.
  • D?partement de Chimie, Universit? de Montr?al, 2900 Boulevard ?douard-Montpetit, Montr?al, Qu?bec, Canada, H3C 3J7.
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Two triorganotin(IV) phosphonate compounds were isolated and structurally investigated by infrared and M?ssbauer spectroscopies and X-ray crystallography. The reactionoftrimethyltin(IV) chloride (SnMe3Cl) and hexamethylenetetraammonium hydrogen methylphosphonate[CH3PO3H][N4(CH2)6H] led to the formation of [C10H34O4P2Sn3] (1) which crystallizes in the Monoclinic space group Pn with Z = 2, a = 8.4955 (2) ?, b = 11.318 (3) ?, c = 11.902 (2) ?, β = 90.9340 (10)? and V = 1144.2 (4) ?3. An uncommon decomposition of methylphosphonate occurred during the reaction process giving rise to the formation of dimers of [SnMe3PH2SnMe3]+. The structure of 1 consists of an anionic chain of [CH3PO3(SnMe3PH2SnMe3)]? linked to [SnMe3(H2O)]+ moieties through Sn?O bonds involving the remaining oxygen atoms of the methylphosphonates. In the chain, each SnMe3 residue is coordinated by one methylphosphonate and one phosphor atom, in a trans-trigonal bipyramidal PSnC3O geometry. The environment at tin atoms in both SnMe3 moieties is an octahedron. The methylphosphonate anion is otherwise in a general position and behaves as a tri-coordinating ligand. The reactionoftriphenyltin(IV) hydroxide (SnPh3OH) and phosphorous acid (HPO(OH)2) led to the formation of [C36H31O3PSn2] (2) which crystallizes in the Monoclinic space group P2/n with Z = 4, a = 11.7966 (4) ?, b = 10.1953 (4) ?, c = 27.6715 (10) ?, β = 94.600 (2)? and V = 3317.3 (2) ?3. The structure of 2 is comprised of an anionic chain of [HPO3(SnPh3)]? linked to SnPh3 moieties through Sn?O bonds involving the remaining oxygen atoms of the hydrogenphosphonates. In the chain the SnPh3 residues are each one coordinated by two hydrogenphosphonates in a trans-trigonal bipyramidal OSnC3O arrangement. The geometry at tin atoms within the monocoordinated SnPh3 moieties connected to the chain is a distorted tetrahedron. The hydrogenphosphonate anion is in a general arrangement and behaves as a tri-O-coordinating ligand.

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[Mouhamadou Birame Diop, Mouhamadou Sembene Boye, Aminata Diasse - Sarr, Libasse Diop, Philippe Guionneau and Thierry Maris. (2019); TRIORGANOTIN PHOSPHONATES POLYMERIC CHAINS - SYNTHESIS, INFRARED, MOSSBAUER AND SINGLE CRYSTAL CHARACTERIZATION:THE FIRST ORGANOTIN(IV) PH2- BRIDGED. Int. J. of Adv. Res. 7 (Aug). 266-278] (ISSN 2320-5407). www.journalijar.com

Mouhamadou Birame Diop
Laboratoire de Chimie Minérale et Analytique (LA.CHI.MI.A.), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop, Dakar, Sénégal

DOI:

Article DOI: 10.21474/IJAR01/9499      
DOI URL: https://dx.doi.org/10.21474/IJAR01/9499

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