15Apr 2018

MECHANISTICALLY CATIONIC MICELLAR CATALYSIS ON THE HYDROLYSIS OF MONO 2,5-DI METHOXY PHENYL PHOSPHORAMIDE.

  • Abanish Kumar and Pratap Singh, Department of Chemistry, BSA College, Mathura, UP, India, 281OO4.
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Hydrolysis of mono- 2,5-dimethoxy phenyl phosphoramide (mono-2,5-DMPP) was studied in micellar solutions of cetyltrimethylammonium bromide (CTABr) at pH-9.0. The hydrolysis followed first order kinetics with respect to mono-2,5DMPP concentration. At the concentration of critical micelle concentration (CMC) the rate of hydrolysis increased with increasing CTABr concentration. The binding constant of micelle for mono-2,5-DMPP and the rate constant in micellar pseudo phase were determined from kinetic data using the pseudo phase model.

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[Gaurav Kumar Singh. (2018); MECHANISTICALLY CATIONIC MICELLAR CATALYSIS ON THE HYDROLYSIS OF MONO 2,5-DI METHOXY PHENYL PHOSPHORAMIDE. Int. J. of Adv. Res. 6 (Apr). 839-844] (ISSN 2320-5407). www.journalijar.com

Dr. ABANISH KUMAR
DEPARTMENT OF CHEMISTRY, BSA COLLEGE, MATHURA, UP INDIA, 281004.

DOI:

Article DOI: 10.21474/IJAR01/6919      
DOI URL: https://dx.doi.org/10.21474/IJAR01/6919

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