31Aug 2017

SYNTHESIS, CHARACTERIZATION, THERMAL AND ANTIMICROBIAL STUDIES OF SCHIFF BASE M(II) COMPLEXES.

  • Department of Chemistry, St. Philomena?s College Bannimantap, Mysuru, Karnataka, India.
  • Department of Chemistry, Yuvaraja?s college, Mysuru, Karnataka, India.
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The N, O type Schiff base ligand and its five new metal complexes of Co(II), Ni(II), Zn(II), Cd(II) and Cu(II) derivatives of 6-acetyl-7 hydroxy 4,8-dimethyl-2H-chromen-2-one have been synthesized from o-phenylenediamine in alcoholic medium. A series of metal complexes have been characterized quantitatively and qualitatively by using micro elemental analysis, FT-IR, 1H NMR, Mass, UV-Vis, TGA/DTG, ESR, magnetic susceptibility data and molar conductance studies. From the spectral study, all the complexes obtained were octahedral in nature. Complexes exhibited enhanced anti-microbial activity in comparison to their ligand.

  1. K. Mandal, K. Nag, J. Chem. Soc. Dalton Trans. 1983.
  2. VinodShelke, M. SarikaJadhav, et al. Journal of the Korean Chemical Society.2011, 55, 3.
  3. L. Pavia, G.M. Lampman, et al. Introduction to Spectroscopy. 3rd ed., Harcourt College Publishers, New York, 2007.
  4. Nishat, Rahis-ud-din, et al. Transition Met.Chem. 2003, 28, 948.
  5. B.H. Howlader, C.M. Zakaria, et al. Jahangirnagar Univ J Sci. 2007, 30, 43.
  6. A. Weber, T.W. Robinson, et al. J. Inorg. Nucl.Chem. 1971, 33, 2097.
  7. D.L. Durantaye, T. Mc Cormick, et al. Dalton Trans. 2006, 66, 5675.
  8. C. Lin, C.C. Huang, et al. Dalton Trans. 2007, 7, 781.
  9. Basak, S. Sen, et al. Polyhedron. 2007, 26, 5104.
  10. Alghool, H.F. Abd El-Halim et al. J. Mol. Struct. 2010, 983, 32.
  11. Garoufis, S.K. Hadjikakou, et al. Coord. Chem. Rev. 2009, 253, 1384.
  12. Naeimi, K. Rabiei, et al. Dyes Pigm. 2007, 75, 294.
  13. Nishihara, Bull. Chem. Soc. Japan. 2004, 77, 407.
  14. Badea, A. Emandi, et al. J. Therm. Anal. Calorim. 2003, 72, 525.
  15. Ispir, Dyes Pigm. 2009, 82, 13.
  16. Asgari-sabet, H. Khoshsima, Dyes Pigm. 2010, 87, 95.
  17. D. Kim, J.H. Cho, et al. Dyes Pigm. 2011, 89, 1.
  18. M.A. Alaghaz, H.A. Bayoumi, et al. J. Mole. Struct. 2013, 1035, 383.
  19. S. Asha, A. Bushra Begum A, Chem. Sci. Rev Lett. 2014, 3, 11, 735-746.
  20. S. Munde, S.G. Shirodkar, et al. Journal of the Korean Chemical Society. 2009, 53, 407.
  21. R. Murray, E.J. Baron, et al.? Manual of Clinical Microbiology. 1995, 6, 118.

22.??? V. Duraipandiyan, S. Ignacimuthu, J. Ethnopharmacol. 2009, 123, 494.

23.??? Dilution Antifungal Susceptibility Testing of Filamentous Fungi, Approved Standard Second Edition CLSI document M38-A2. Clinical and Laboratory Standards Institute, USA. 2008, 28, 1.

  1. Sreekanth and M.R.P. Kurup, Polyhedron, 2003, 23, 3321.
  2. N. Prasad, M. Mathur, et al. J. Indian Chem. Soc. 2007, 84, 1202.
  3. A. Faniran, K.S. Patel, et al.J. Inorg. Nucl.Chem. 1974, 36, 1547.
  4. VinodShelke, Sarika M. et al. Journal of the Korean Chemical Society. 2011, 55, 3.
  5. K. Mandal, K. Nag, J. Chem. Soc. Dalton Trans. 1983.
  6. VinodShelke, M. SarikaJadhav, et al. Journal of the Korean Chemical Society. 2011, 55, 3.
  7. L. Pavia, G.M. Lampman, et al. Introduction to Spectroscopy, 3rd ed., Harcourt College Publishers, New York, 2007.
  8. Nishat, Rahis-ud-din, et al. Transition Met.Chem. 2003, 28, 948.
  9. B.H. Howlader, C. M. Zakariaet al. Jahangirnagar Univ J Sci, 2007, 30, 43.
  10. P. Singh, V. Malik, et al. Russ. J. Coord. Chem. 2009, 35, 740.
  11. Chandra, R. Kumar, Transition Met. Chem. 2004, 29, 269
  12. P. Singh, V. Malik, et al. Russ. J. Coord. Chem. 2009, 35, 740.
  13. P. Singh, K. Kumar, et al. J. Enzym, Inhib. Med. Chem. 2009, 24, 795.
  14. Yamashita, J.B. Fenn, J. Phys. Chem. 1984, 88, 4451.
  15. Abe, K. Matsufuji, et al. Inorganic Chemistry. 2002, 41, 4461.
  16. Chandra, L.K. Gupta. Spectrochim. Acta A. 2005, 61, 269.
 

[Asha M S, OthbertPinto, Joseph N Sebastian, Sumana Naik, Shaukath Ara Khanum* (2017); SYNTHESIS, CHARACTERIZATION, THERMAL AND ANTIMICROBIAL STUDIES OF SCHIFF BASE M(II) COMPLEXES. Int. J. of Adv. Res. 5 (Aug). 2189-2204] (ISSN 2320-5407). www.journalijar.com

Dr. Shaukath Ara Khanum
Department of Chemistry, Yuvaraja’s college, Mysuru, Karnataka, India.

DOI:

Article DOI: 10.21474/IJAR01/5286      
DOI URL: https://dx.doi.org/10.21474/IJAR01/5286

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