25Apr 2017

SPECTROSCOPIC DETERMINATION OF SOME HEAVY METALS AND THEIR EFFECT ON THE QUALITY OF GROUNDWATER.

  • Chemistry Department, Faculty of science, Suez University, Suez city, Egypt.
  • Chemistry Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt.
Crossref Cited-by Linking logo
  • Abstract
  • Keywords
  • References
  • Cite This Article as
  • Corresponding Author

Heavy metal contamination of the groundwater of Upper Egypt was described. The groundwater samples were analyzed for some heavy metals (Mn, Fe, Cu, Zn, Cd, and Pb), by atomic absorption. Determine the water quality of ground water which is used for drinking and agriculture operations in the study area. Water samples from fourteen groundwater wells were collected for one year period (October 2014 to September 2015). According to WHO limited for drinking water, results showed that only the concentration of Cu and Zn are within the saving values. On the other hand concentration of Mn, Fe, Zn, Cd and Pb are found to be higher than the allowed WHO limits of the water samples analyzed. The autumn months record the highest concentration for each Mn, Fe, Cd and Pb (3.58, 10.09, 1.04 and 14.08 mg/l) respectively, denoting that metal concentration in the wells vary significantly with sampling time. From the data we can observed that concentrations of the heavy metals vary significantly between the different ground water wells, indicating that the wells are different from each other in terms of heavy metal content. The results of this study suggest a possible risk to the population of the study area given the toxicity of these metals, and the fact that for many people in the study area, ground water is a main source of their water supply.


  1. Bassioni, K.Ashraf, A.Abd Elhameed, Risk assessment using ICP-MS of heavy metals in groundwater in Upper Egypt ,Journal of Natural Resources and Development, Vol. 5 2015, 65-70
  2. A. Momodu and C. A. Anyakora, ?Heavy Metal Con- tamination of Ground Water: The Surulere Case Study,?Research Journal Environmental and Earth Sciences, Vol. 2, No. 1, 2010, 39-43.
  3. K. Vodela, J. A. Renden, S. D. Lenz, W. H. Mchel Henney and B. W. Kemppainen, ?Drinking Water Contaminates,? Poultry Science, Vol. 76, No. 11, 1997,. 1474-1492.
  4. R. Mason, ?Groundwater pollution, prevention and control,? Environ. Manage. Issues, 2012
  5. United States Environmental Protection Agency (US EPA). 2012 Edition of the Drinking Water Standards and Health Advisories. Office of Water U.S. Environmental Protection Agency Washington, DC, pp. 1-10, 2012.
  6. R. Bhagure, S. R. Mirgane. Heavy metal concentrations in groundwaters and soils of Thane Region of Maharashtra, India.?Environ Monit Assess.?2011,173, 643?652.
  7. G. Vaishaly,B. B. Mathew* and N.B. Krishnamurthy Health effects caused by metal contaminated ground water International Journal of Advances in Scientific Research 2015; 1(02): 60-64.
  8. J. Ferner, ?Toxicity and Heavy Metals,? eMedicine Journal, Vol. 2, No. 5, 2001, p. 1.
  9. Dupler, ?Heavy Metal Poisoning,? In: J. L. Longe, Ed., Gale Encyclopedia of Alternative Medicine, Gale Group, Farmington Hills, 2001, 2054-2057
  10. L. He, XE Yang, PJ Stoffella. Trace elements in agroecosystems and impacts on the environment.?J Trace Elem Med Biol.19,?2005; 125?140
  11. Egyptian Environmental Affairs Agency (EEAA) Law Number 48 of 1982 Promulgating the Environmental Law. Regulations to the Minister of Water Resources and Irrigation, 2009.
  12. Mohammed, S. Sadeek , A.R.Mahmoud , D Zaky ,Comparison of AAS, EDXRF, ICP-MS and INAA performance for determination of selected heavy metals in HFO ashes Microchemical Journal 128 (2016) 1?6
  13. H. Duffus. Heavy metals-a meaningless term?Pure Appl Chem.?2002; 74(5):793?807.
  14. Belkhiria, L. Mounib , T. S. Naranyc , A. Tiria, Evaluation of potential health risk of heavy metals in groundwater using the integration of indicator kriging and multivariate statistical methodsGroundwater for Sustainable Development 4 (2017) 12?22
  15. Abdelfattah, A.A. Ismail, F.Al Sayed, A.Almedolab, K.M. Aboelghait, Biosorption of heavy metals ions in real industrial wastewater using peanut husk as efficient and cost effective adsorbent Environmental Nanotechnology, Monitoring & Management 6 (2016) 176?183
  16. Guidelines for drinking water quality, second ed.vol.2.Health criteria and other supporting information, Geneva, WHO (1996).
  17. Vella, , R. Malaguarnera, , R. Lappano, M. Maggiolini , A. Belfiore, Recent views of heavy metals as possible risk factors and potential preventive and therapeutic agents in prostate cance Molecular and Cellular Endocrinology (2016) 1-16.
  18. E. Achanzar, B. A Diwan, J Liu, S.T Quader, M. M Webber, M. P Waalkes, 2001. Cadmium-induced malignant transformation of human prostate epithelial cells. Cancer Res. 61, 455-458
  19. Muhammad, T. Shah , S. Khan, Health risk assessment of heavy metals and their source apportionment in drinking water of Kohistan region, northern Pakistan,Microchemical Journal 98 (2011) 334?343
  20. Xing , L. Guangyang, Q. Fangshu , L. Kai , S. Shao , L. Guibai, H. Liang, Removal of iron, manganese and ammonia from groundwater using a PAC-MBR system: The anti-pollution ability, microbial population and membrane fouling Desalination 403 (2017) 97?106
  21. Li, S. Wang, X. Du, X. Cheng, M. Fu, N. Hou, D. Li, Immobilization of iron- and manganese-oxidizing bacteria with a biofilm-forming bacterium for the effective removal of iron and manganese from groundwater Bioresource Technology 220 (2016) 76?84
  22. Huang, C.-D. Dong, C. Chen, R. Surampalli, Application of sulfate reduction mechanisms for the simultaneous bioremediation of toluene and copper contaminated groundwaterhih-Ming Kao International Biodeterioration & Biodegradation xxx (2017) 1e8.
  23. Pullin, R. A. Crane, D. J. Morgan, T. B. Scott, The effect of common groundwater anions on the aqueous corrosion of zero-valent iron nanoparticles and associated removal of aqueous copper and zinc Journal of Environmental Chemical Engineering 5 (2017) 1166?1173.
  24. Chunfa, L. Yongming, S. Deng, Y. Teng, J. Song Spatial characteristics of cadmium in topsoils in a typical e-waste recycling area in southeast China and its potential threat to shallow, groundwater Science of the Total Environment 472 (2014) 556?561.
  25. Rongbing, Y. Yang, X. Zhen, X. Zhang, X. Guo, B. Dongsu, The removal of chromium (VI) and lead (II) from groundwater using sepiolite-supported nanoscale zero-valent iron (S-NZVI) Chemosphere 138 (2015) 726?734.

[R. M. Abd El-aal, W. H. Hegazy, I. A. Ibrahem and M. A. Esmail1. (2017); SPECTROSCOPIC DETERMINATION OF SOME HEAVY METALS AND THEIR EFFECT ON THE QUALITY OF GROUNDWATER. Int. J. of Adv. Res. 5 (Apr). 1276-1289] (ISSN 2320-5407). www.journalijar.com


I.A. Ibrahem
Chemistry Department. Faculty of Science, Al - Azhar University. Nasr City. Cairo. Egypt.

DOI:


Article DOI: 10.21474/IJAR01/3945      
DOI URL: https://dx.doi.org/10.21474/IJAR01/3945