SYNTHESIS AND CHARACTERIZATION OF (1E, 2E) - 1, 2 - DIPHENYLETHANE -1, 2 – DIENEHYDRAZONE OXIME LIGAND AND ITS Fe(II) AND Pd(II) METAL COMPLEXES.
- Schoolof Basic Sciences, Jaipur National University, Jaipur-302017, India.
- Department of Chemistry, K.M.Agrawal College, Kalyan-421301, India.
- Department of Chemistry, Institute of Science 15, Madam Cama Road, Mumbai- 400032, India.
- Abstract
- Keywords
- Cite This Article as
- Corresponding Author
Reaction between hydrazine hydrate 80% aqueous solution and an alcoholic solution of ?-benzilmonoxime yields ?-benzilmonoximehydrazone (IUPAC Name: (1E, 2E) - 1, 2 - diphenylethane -1, 2 –diene hydrazine oxime). The present work report the synthesis and characterization of ?-benzilmonoximehydrazone along with its metal complexes with Fe(II) and Pd(II). The compounds synthesized have been characterized on the basis of various physico-chemical techniques. Electrical conductance studies on the metal complexes reveal their non-electrolytic nature. Spectral measurements and magnetic moment suggest an octahedral geometry for Fe(II) Complex, and square planar geometry for Pd(II) complex. Reaction between hydrazine hydrate 80% aqueous solution and an alcoholic solution of ?-benzilmonoxime yields ?-benzilmonoximehydrazone (IUPAC Name: (1E, 2E) - 1, 2 - diphenylethane -1, 2 –diene hydrazine oxime). The present work report the synthesis and characterization of ?-benzilmonoximehydrazone along with its metal complexes with Fe(II) and Pd(II). The compounds synthesized have been characterized on the basis of various physico-chemical techniques. Electrical conductance studies on the metal complexes reveal their non-electrolytic nature. Spectral measurements and magnetic moment suggest an octahedral geometry for Fe(II) Complex, and square planar geometry for Pd(II) complex.
[Raj R. Badekar, R. S. Lokhande, S. W. Kulkarni and R. M. Patil. (2016); SYNTHESIS AND CHARACTERIZATION OF (1E, 2E) - 1, 2 - DIPHENYLETHANE -1, 2 – DIENEHYDRAZONE OXIME LIGAND AND ITS Fe(II) AND Pd(II) METAL COMPLEXES. Int. J. of Adv. Res. 4 (Aug). 796-800] (ISSN 2320-5407). www.journalijar.com
