18Sep 2017
VOLTAMMETRIC STRUCTURE-ACTIVITY QUANTIFICATION OF REGIO-ISOMERS OF DIHYDROXYBENZOIC ACID: ELUCIDATION OF STERIC CONSTRAINTS DURING RAPID IODINATION BY AQUEOUS SOLUTIONS DEVOID OF IODIDE IONS.
- Post-Graduate Department of Chemistry, NowrosjeeWadia College, Affiliated to the SavitribaiPhule University, Pune- 411001, India.
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The reactivity of three regio-isomers of dihydroxybenzoic acid in aqueous medium has been assessed on a quantitative scaffold by voltammetry. The rapid iodination kinetics of these isomers by aqueous molecular iodine solutions devoid of iodide ions has been investigated and the data invoked to elucidate the steric compulsions in the dynamics of these reactions.
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[R. P. Yadav, B. B. Bahule, V. T. Borkar and *V. T. Dangat. (2017); VOLTAMMETRIC STRUCTURE-ACTIVITY QUANTIFICATION OF REGIO-ISOMERS OF DIHYDROXYBENZOIC ACID: ELUCIDATION OF STERIC CONSTRAINTS DURING RAPID IODINATION BY AQUEOUS SOLUTIONS DEVOID OF IODIDE IONS. Int. J. of Adv. Res. 5 (Sep). 856-860] (ISSN 2320-5407). www.journalijar.com
V.T.DANGAT
Post-Graduate Department of Chemistry, Nowrosjee Wadia College,
Post-Graduate Department of Chemistry, Nowrosjee Wadia College,